研究者情報 - 清水　章弘

シミズ　アキヒロ SHIMIZU Akihiro
清水　章弘

所属

青山学院大学理工学部化学・生命科学科

職種教授

研究業績（著書・論文等）
1.	著書	Redox-Active Molecules and Their Energy Device Application, Sustainable and Functional Redox Chemistry (Issn) Royal Society of Chemistry (単著) 2022/04/29
2.	著書	新規カチオンプール法による有機電解合成、有機電解合成の新潮流 (ファインケミカルシリーズ) シーエムシー出版 (共著) 2021/11/25
3.	著書	The recent developments of electrochemical oxidation Green Oxidation in Organic Synthesis,409-437頁 (共著) 2019/07/12
4.	著書	Singlet open-shell character of polyperiacenes Graphene and its Fascinating Attributes,45-57頁 (共著) 2011/01/01
5.	論文	Synthesis, characterization, and magnetic interactions of carbazole-9-oxyl and its derivatives Bulletin of the Chemical Society of Japan (共著) 2025/07/30
6.	論文	Multiple Near‐Infrared Chromisms of a Heteromerous Overcrowded Ethylene with Large Permanent Dipole Moment Angewandte Chemie International Edition (共著) 2025/03/24
7.	論文	m-Quinodimethane-Based Fused-Ring Diradicals with Singlet and Triplet Ground States Chemistry 7 (2),40-40頁 (単著) 2025/03/13
8.	論文	m-キノジメタンを基盤とする縮合多環ジラジカルの創出有機合成化学協会誌 82 (1),27-36頁 (単著) 2024/01/01
9.	論文	Zwitterionic Open‐Shell Singlet Diradical with Solvent‐Dependent Singlet–Triplet Energy Gap Asian Journal of Organic Chemistry (共著) 2023/06/06
10.	論文	A Kinetically Stabilized Nitrogen‐Doped Triangulene Cation: Stable and NIR Fluorescent Diradical Cation with Triplet Ground State Angewandte Chemie International Edition (共著) 2023/05/22
11.	論文	m-Quinodimethane-based fused-ring triplet hydrocarbons Pure and Applied Chemistry (単著) 2023
12.	論文	Synthesis and Isolation of a Kekulé Hydrocarbon with a Triplet Ground State Angewandte Chemie International Edition (共著) 2022/05/31
13.	論文	Synthesis and Isolation of a Kinetically Stabilized Crystalline Triangulene Journal of the American Chemical Society (共著) 2021/11/24
14.	論文	Anthracene-Based Zwitterion with a Small HOMO–LUMO Energy Gap Synthesis (共著) 2021/11/02
15.	論文	HOMO–LUMO Energy-Gap Tuning of π-Conjugated Zwitterions Composed of Electron-Donating Anion and Electron-Accepting Cation The Journal of Organic Chemistry 86 (1),770-781頁 (共著) 2021/01/01
16.	論文	Metal-Free Twofold Electrochemical C-H Amination of Activated Arenes: Application to Medicinally Relevant Precursor Synthesis CHEMISTRY-A EUROPEAN JOURNAL 26 (72),17574-17580頁 (共著) 2020/12
17.	論文	Azoniadibenzo[a,j]phenalenide: A Polycyclic Zwitterion with Singlet Biradical Character Angewandte Chemie International Edition 58 (19),6415-6419頁 (共著) 2019/05/06
18.	論文	Metal- and Oxidant-Free Alkenyl C−H/Aromatic C−H Cross-Coupling Using Electrochemically Generated Iodosulfonium Ions Angewandte Chemie International Edition 57 (39),12891 (共著) 2018/09/24
19.	論文	Electrogenerated Cationic Reactive Intermediates: The Pool Method and Further Advances Chemical Reviews 118 (9),4702-4730頁 (共著) 2018/05/09
20.	論文	Development of Electroorganic Reactions Utilizing Stabilized Reactive Species and Its Application to Organic Energy Storage Materials Electrochemistry (単著) 2018
21.	論文	Generation and reactions of thiirenium ions by the Cation Pool method ARKIVOC,97-113頁 (共著) 2018
22.	論文	Liquid Quinones for Solvent-Free Redox Flow Batteries ADVANCED MATERIALS 29 (41) (共著) 2017/11
23.	論文	New Approach to 1,4-Benzoxazin-3-ones by Electrochemical C-H Amination CHEMISTRY-A EUROPEAN JOURNAL 23 (50),12096-12099頁 (共著) 2017/09
24.	論文	Fluoreno[2,3-b]fluorene vs Indeno[2,1-b]fluorene: Unusual Relationship between the Number of pi Electrons and Excitation Energy in m-Quinodimethane-Type Singlet Diradicaloids JOURNAL OF ORGANIC CHEMISTRY 82 (3),1380-1388頁 (共著) 2017/02
25.	論文	Metal-Free Benzylic C-H Amination via Electrochemically Generated Benzylaminosulfonium Ions CHEMISTRY-A EUROPEAN JOURNAL 23 (1),61-64頁 (共著) 2017/01
26.	論文	The Stabilized Cation Pool Method: Metal- and Oxidant-Free Benzylic C-H/Aromatic C-H Cross-Coupling JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138 (27),8400-8403頁 (共著) 2016/07
27.	論文	Generation, Characterization, and Reactions of Thionium Ions Based on the Indirect Cation Pool Method BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 89 (1),61-66頁 (共著) 2016/01
28.	論文	有機レドックス・フロー電池材料の開発 (特集低炭素化技術開発の展望) ケミカルエンジニヤリング = Chemical engineering 61 (3),187-192頁 (共著) 2016/01
29.	論文	PPV Polymerization through the Gilch Route: Diradical Character of Monomers CHEMISTRY-A EUROPEAN JOURNAL 21 (52),19176-19185頁 (共著) 2015/12
30.	論文	Heterocyclization Approach for Electrooxidative Coupling of Functional Primary Alkylamines with Aromatics JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137 (31),9816-9819頁 (共著) 2015/08
31.	論文	Reaction Integration Using Electrogenerated Cationic Intermediates BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 88 (6),763-775頁 (共著) 2015/06
32.	論文	Automated Electrochemical Assembly of the Protected Potential TMG-chitotriomycin Precursor Based on Rational Optimization of the Carbohydrate Building Block ORGANIC LETTERS 17 (6),1525-1528頁 (共著) 2015/03
33.	論文	Electrochemical Intramolecular C-H Amination: Synthesis of Benzoxazoles and Benzothiazoles CHEMISTRY-A EUROPEAN JOURNAL 21 (8),3211-3214頁 (共著) 2015/02
34.	論文	Switching the reaction pathways of electrochemically generated beta-haloalkoxysulfonium ions - synthesis of halohydrins and epoxides BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 11 (Feb),242-248頁 (共著) 2015/02
35.	論文	Tetracyclopenta[def,jkl,pqr,vwx]tetraphenylene: A Potential Tetraradicaloid Hydrocarbon ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54 (7),2090-2094頁 (共著) 2015/02
36.	論文	Non-alternant non-benzenoid kekulenes: the birth of a new kekulene family CHEMICAL SOCIETY REVIEWS 44 (18),6560-6577頁 (共著) 2015
37.	論文	Redox active dendronized polystyrenes equipped with peripheral triarylamines BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 10,3097-3103頁 (共著) 2014/12
38.	論文	Transformation of octadehydrodibenzo[12]annulene to benzonaphthopentalene by successive nucleophilic and electrophilic transannular cyclizations TETRAHEDRON 70 (45),8474-8479頁 (共著) 2014/11
39.	論文	Introduction of two lithiooxycarbonyl groups enhances cyclability of lithium batteries with organic cathode materials JOURNAL OF POWER SOURCES 260,211-217頁 (共著) 2014/08
40.	論文	Indenofluorene congeners: Biradicaloids and beyond PURE AND APPLIED CHEMISTRY 86 (4),517-528頁 (共著) 2014/04
41.	論文	Direct C-N Coupling of Imidazoles with Aromatic and Benzylic Compounds via Electrooxidative C-H Functionalization JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136 (12),4496-4499頁 (共著) 2014/03
42.	論文	Nitrogen-Containing Polycyclic Quinones as Cathode Materials for Lithium-ion Batteries with Increased Voltage ENERGY TECHNOLOGY 2 (2),155-158頁 (共著) 2014/02
43.	論文	4. キノンを基本骨格とする正極活物質を用いる有機二次電池 Electrochemistry 82 (8) (共著) 2014/01
44.	論文	Benz[c] indeno[2,1-a] fluorene: a 2,3-naphthoquinodimethane incorporated into an indenofluorene frame CHEMICAL SCIENCE 5 (1),163-168頁 (共著) 2014
45.	論文	Synthesis and physical properties of zethrene derivatives bearing donor/acceptor substituents at 7,14-positions ORGANIC & BIOMOLECULAR CHEMISTRY 11 (47),8256-8261頁 (共著) 2013/12
46.	論文	Halogen and Chalcogen Cation Pools Stabilized by DMSO. Versatile Reagents for Alkene Difunctionalization JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135 (43),16070-16073頁 (共著) 2013/10
47.	論文	Automated Solution-Phase Synthesis of Oligosaccharides via Iterative Electrochemical Assembly of Thioglycosides ORGANIC LETTERS 15 (17),4520-4523頁 (共著) 2013/09
48.	論文	Electrochemical C-H amination: Synthesis of aromatic primary amines via N -arylpyridinium ions Journal of the American Chemical Society 135 (13),5000-5003頁 (共著) 2013/04/03
49.	論文	Indeno[2,1-b]fluorene: A 20-pi-Electron Hydrocarbon with Very Low-Energy Light Absorption ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 (23),6076-6079頁 (共著) 2013
50.	論文	Oxidative Cyclodimerization After Tandem Cyclization of Dehydrobenzo[14]annulenes Induced by Alkyllithium ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52 (15),4184-4188頁 (共著) 2013
51.	論文	Polymer-Bound Pyrene-4,5,9,10-tetraone for Fast-Charge and -Discharge Lithium-Ion Batteries with High Capacity JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134 (48),19694-19700頁 (共著) 2012/12
52.	論文	Aromaticity and pi-bond covalency: prominent intermolecular covalent bonding interaction of a Kekule hydrocarbon with very significant singlet biradical character CHEMICAL COMMUNICATIONS 48 (45),5629-5631頁 (共著) 2012
53.	論文	Metal- and Chemical-Oxidant-Free C-H/C-H Cross-Coupling of Aromatic Compounds: The Use of Radical-Cation Pools ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 51 (29),7259-7262頁 (共著) 2012
54.	論文	Singlet Open-Shell Character of Conjugated Kekule Molecules INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING 2009 (ICCMSE 2009) 1504,883-886頁 (共著) 2012
55.	論文	Theoretical Aspects on the Evaluation and Interpretation of the Third-Order Nonlinear Optical Properties of Diradical Compounds INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING 2009 (ICCMSE 2009) 1504,844-847頁 (共著) 2012
56.	論文	Theoretical Consideration of Singlet Open-Shell Character of Polyperiacenes Using Clar's Aromatic Sextet Valence Bond Model and Quantum Chemical Calculations INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING 2009 (ICCMSE 2009) 1504,399-405頁 (共著) 2012
57.	論文	Experimental consideration of covalent-bonding interactions in stacks of singlet biradicals having Kekule structures JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 24 (10),876-882頁 (共著) 2011/10
58.	論文	Synthesis, Crystal Structure, and Physical Properties of Sterically Unprotected Hydrocarbon Radicals JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133 (36),14240-14243頁 (共著) 2011/09
59.	論文	ChemInform Abstract: Experimental Consideration of Covalent Bonding Interactions in Stacks of Singlet Biradicals Having Kekule Structures ChemInform 43 (2),no (共著) 2011
60.	論文	Indeno[2,1-a]fluorene: An Air-Stable ortho-Quinodimethane Derivative ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 50 (30),6906-6910頁 (共著) 2011
61.	論文	Electronic structure of delocalized singlet biradical Ph2-IDPL solid film Physical Chemistry Chemical Physics 12 (39),12570-12577頁 (共著) 2010/10/21
62.	論文	Alternating Covalent Bonding Interactions in a One-Dimensional Chain of a Phenalenyl-Based Singlet Biradical Molecule Having Kekule Structures JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132 (41),14421-14428頁 (共著) 2010/10
63.	論文	Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekule Structures JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132 (32),11021-11023頁 (共著) 2010/08
64.	論文	Signature of multiradical character in second hyperpolarizabilities of rectangular graphene nanoflakes CHEMICAL PHYSICS LETTERS 489 (4-6),212-218頁 (共著) 2010/04
65.	論文	Singlet Diradical Character from Experiment JOURNAL OF PHYSICAL CHEMISTRY LETTERS 1 (6),937-940頁 (共著) 2010/03
66.	論文	Chemistry of Phenalenyl-based Delocalized Singlet Biradicals JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 68 (1),64-74頁 (共著) 2010/01
67.	論文	Synthesis, Structure, and Photophysical Properties of Dibenzo[de,mn]naphthacenes ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 49 (39),7059-7062頁 (共著) 2010
68.	論文	Third-order nonlinear optical properties of trigonal, rhombic and bow-tie graphene nanoflakes with strong structural dependence of diradical character CHEMICAL PHYSICS LETTERS 480 (4-6),278-283頁 (共著) 2009/10
69.	論文	Scanning Tunneling Microscopy Study of a Phenalenyl-Based Singlet Biradical on Graphite JOURNAL OF PHYSICAL CHEMISTRY C 113 (4),1515-1519頁 (共著) 2009/01
70.	論文	Resonance Balance Shift in Stacks of Delocalized Singlet Biradicals ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 48 (30),5482-5486頁 (共著) 2009
71.	論文	Theoretical study of third-order nonlinear optical properties in square nanographenes with open-shell singlet ground states CHEMICAL PHYSICS LETTERS 467 (1-3),120-125頁 (共著) 2008/12
72.	論文	Ambipolar organic field-effect transistors based on a low band gap semiconductor with balanced hole and electron mobilities APPLIED PHYSICS LETTERS 91 (4) (共著) 2007/07
73.	論文	Singlet biradical character of phenalenyl-based Kekule hydrocarbon with naphthoquinoid structure ORGANIC LETTERS 9 (1),81-84頁 (共著) 2007/01
74.	論文	Strong two-photon absorption of singlet diradical hydrocarbons ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 46 (19),3544-3546頁 (共著) 2007
75.	論文	Synthesis, intermolecular interaction, and semiconductive behavior of a delocalized singlet biradical hydrocarbon Angewandte Chemie - International Edition 44 (40),6564-6568頁 (共著) 2005/10/14